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4-hydroxybenzenesulphonic acid

phenol-4-sulfonic acid

CAS: 98-67-9

Molecular Formula: C6H6O4S

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4-hydroxybenzenesulphonic acid - Names and Identifiers

Name phenol-4-sulfonic acid
Synonyms ARADUR 5003-1 BD
phenol sulphonate
Phenolsulfuric Acid
4-phenolsulfonicacid
4-Phenolsulfonic acid
phenol-4-sulfonic acid
phenol-p-sulphonic acid
4-hydroxyphenylsulfonicacid
4-hydroxy-benzenesulfonicaci
Phenol-4-sulfonicacidsolutio
4-Hydroxyphenylsulfonic acid
p-Phenolsulfonic acid hydrate
4-hydroxybenzenesulfonic acid
4-hydroxy-benzenesulfonicacid
p-Hydroxybenzenesulfonic acid
4-hydroxybenzenesulphonic acid
p-hydoroxybenzenesulfonic acid
Benzenesulfonicacid,4-hydroxy-
Benzenesulfonic acid, p-hydroxy-
4-(4-hydroxyphenyl)azobenzenesulfonic acid
CAS 98-67-9
EINECS 202-691-6
InChI 1S/C6H6O4S/c7-5-1-3-6(4-2-5)11(8,9)10/h1-4,7H,(H,8,9,10)
InChIKey FEPBITJSIHRMRT-UHFFFAOYSA-N

4-hydroxybenzenesulphonic acid - Physico-chemical Properties

Molecular FormulaC6H6O4S
Molar Mass174.17
Density1.337g/mLat 25°C
Melting Point52 °C
Boling Point275.14°C (rough estimate)
Water SolubilitySoluble in water.
Vapor Presure69.8Pa at 20℃
AppearanceLiquid
Specific Gravity1.337
ColorWhite to Light yellow to Light red
Merck14,7246
BRN1869034
pKa9.11(at 25℃)
StabilityStable. Combustible. Incompatible with strong oxidizing agents.
Refractive Indexn20/D 1.489

4-hydroxybenzenesulphonic acid - Risk and Safety

Hazard SymbolsC - Corrosive
Corrosive
Risk CodesR34 - Causes burns
R68 - Possible risk of irreversible effects
Safety DescriptionS26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDsUN 2586 8/PG 3
WGK Germany-
RTECSDB6970000
TSCAYes
HS Code29089990
Hazard Class8
Packing GroupIII

4-hydroxybenzenesulphonic acid - Reference Information

LogP0.41 at 25℃
NIST chemical information information provided by: webbook.nist.gov (external link)
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
Introduction p-hydroxybenzenesulfonic acid (4-hydroxybenzenesulfonic acid) is white crystalline powder, soluble in water, hot alcohol and glycerol. Sodium p-hydroxybenzenesulfonate is a very important intermediate in organic synthesis and pharmaceutical industry, and its research value and commercial value are gradually found.
Application p-hydroxybenzenesulfonic acid is the most important additive in acid tin plating process, and also has the effect of acid resin foaming, used as casting resin curing agent at room temperature.
preparation take 100g of mesitylene, add 78g of phenol to it, heat to 65 °c in a water bath, add 4g of phosphorous acid as a catalyst, add the raw material into the feed tank at one time, add 82g of concentrated sulfuric acid into the concentrated sulfuric acid feed tank, make n(H2SO4):n(C6H6O)= 1:1,n(C9H12):n(C6H6O)= 1:1. The temperature was increased to 100 °c. The stirrer and the high-gravity reactor were turned on, the rotor speed of the high-gravity reactor was adjusted, and the rotation speed of the high-gravity reactor 10 was maintained at 2000rpm. After the temperature and equipment were stabilized, the feed was started at a feed rate of 250ml/min, the feed was completed, and the circulation was 3min to obtain p-hydroxybenzenesulfonic acid.
Application for resin curing
is the most important additive in acid tin plating process, at the same time also has the role of acidic resin foaming
used as casting resin curing agent at room temperature
organic intermediates.
toxic substance data information provided by: pubchem.ncbi.nlm.nih.gov (external link)
Last Update:2024-05-11 14:05:09
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